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Air Emission Event Report Database Incident 350680

Incident Tracking Number: 350680 Incident Status: CLOSED
Report Type: FINAL Report Date: 03/04/2021
Name of Owner or Operator: EXXON MOBIL CORPORATION CN: CN600123939
Regulated Entity Name: EXXON MOBIL CHEMICAL BAYTOWN OLEFINS PLANT RN: RN102212925
Physical Location: 3525 DECKER DR; BAYTOWN, TX 77520
County: HARRIS
Event/Activity Type: EMISSIONS EVENT
Date and Time Event Discovered or Scheduled Activity Start: 02/15/2021 03:09 AM
Date and Time Event or Scheduled Activity Ended: 02/18/2021 12:59 AM
Event Duration: 69 hours, 50 minutes
Process Unit or Area Common Names
Olefins Plant Operating Units
Facility Common Name Facility Identification Number (FIN)
ExxonMobil Baytown Olefins Plant BOP
1 - Emission Point Common Name: Emission Point Number:
BOP-XX Furnaces BOPXXFURNACE
List of Air Contaminant Compounds - 1 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
Nitrogen Oxides 778.01 POUNDS 45.2 LBS/HR 537.74 lbs of the total 778.01 lbs are authorized under Permit #102982.
2 - Emission Point Common Name: Emission Point Number:
Elevated Flare FLAREXX1
List of Air Contaminant Compounds - 17 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 97.98 POUNDS 371.9 LBS/HR 97.98 lbs of the total 97.98 lbs are authorized under Permit #102982.
1-Butene 10.84 POUNDS 371.9 LBS/HR 10.84 lbs of the total 10.84 lbs are authorized under Permit #102982.
Acetylene 13.54 POUNDS 371.9 LBS/HR 13.54 lbs of the total 13.54 lbs are authorized under Permit #102982.
Benzene 43.43 POUNDS 371.9 LBS/HR 43.43 lbs of the total 43.43 lbs are authorized under Permit #102982.
Butane, N- 10.91 POUNDS 371.9 LBS/HR 10.91 lbs of the total 10.91 lbs are authorized under Permit #102982.
C5s 33.39 POUNDS 371.9 LBS/HR 33.39 lbs of the total 33.39 lbs are authorized under Permit #102982.
C6+ 138.02 POUNDS 371.9 LBS/HR 138.02 lbs of the total 138.02 lbs are authorized under Permit #102982.
Carbon Monoxide 1947.9 POUNDS 160.64 LBS/HR 1947.90 lbs of the total 1947.90 lbs are authorized under Permit #102982.
Cis-2-butene 8.8 POUNDS 371.9 LBS/HR 8.80 lbs of the total 8.80 lbs are authorized under Permit #102982.
Ethylene (gaseous) 1376.65 POUNDS 371.9 LBS/HR 1376.65 lbs of the total 1376.65 lbs are authorized under Permit #102982.
Isobutane 0.03 POUNDS 371.9 LBS/HR 0.03 lbs of the total 0.03 lbs are authorized under Permit #102982.
Isobutene 0.76 POUNDS 371.9 LBS/HR 0.76 lbs of the total 0.76 lbs are authorized under Permit #102982.
Nitrogen Oxides 315.98 POUNDS 22.24 LBS/HR 285.81 lbs of the total 315.98 lbs are authorized under Permit #102982.
Propane 5.37 POUNDS 371.9 LBS/HR 5.37 lbs of the total 5.37 lbs are authorized under Permit #102982.
Propylene (Propene) 49.09 POUNDS 371.9 LBS/HR 49.09 lbs of the total 49.09 lbs are authorized under Permit #102982.
Sulfur dioxide 72.44 POUNDS 7.97 LBS/HR 72.44 lbs of the total 72.44 lbs are authorized under Permit #102982.
Trans-2-butene 5.84 POUNDS 371.9 LBS/HR 5.84 lbs of the total 5.84 lbs are authorized under Permit #102982.
3 - Emission Point Common Name: Emission Point Number:
Expansion Flare FLAREX
List of Air Contaminant Compounds - 18 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 373.99 POUNDS 709.48 LBS/HR 249.70 lbs of the total 373.99 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Acetylene 23.15 POUNDS 709.48 LBS/HR 14.17 lbs of the total 23.15 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Benzene 40.2 POUNDS 709.48 LBS/HR 19.41 lbs of the total 40.20 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Butane, N- 522.57 POUNDS 709.48 LBS/HR 326.56 lbs of the total 522.57 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C10s 2.09 POUNDS 709.48 LBS/HR 1.49 lbs of the total 2.09 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C5s 223.53 POUNDS 709.48 LBS/HR 160.15 lbs of the total 223.53 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C6 (not including benzene) 257.73 POUNDS 709.48 LBS/HR 184.66 lbs of the total 257.73 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C7s 63.96 POUNDS 709.48 LBS/HR 45.82 lbs of the total 63.96 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C8s 77.03 POUNDS 709.48 LBS/HR 55.19 lbs of the total 77.03 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Carbon Monoxide 18558.69 POUNDS 6627.58 LBS/HR 8307.00 lbs of the total 18558.69 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Cis-2-butene 32.43 POUNDS 709.48 LBS/HR 20.47 lbs of the total 32.43 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Ethylene 6249.64 POUNDS 709.48 LBS/HR 3993.84 lbs of the total 6249.64 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutane 47.55 POUNDS 709.48 LBS/HR 30.85 lbs of the total 47.55 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutene 151.48 POUNDS 709.48 LBS/HR 95.25 lbs of the total 151.48 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Nitrogen Oxides 2653.72 POUNDS 1630.75 LBS/HR 1897.89 lbs of the total 2653.72 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propane 235.8 POUNDS 709.48 LBS/HR 174.58 lbs of the total 235.80 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propylene (Propene) 1406.49 POUNDS 709.48 LBS/HR 950.86 lbs of the total 1406.49 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Trans-2-butene 76.75 POUNDS 709.48 LBS/HR 50.99 lbs of the total 76.75 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
4 - Emission Point Common Name: Emission Point Number:
LC-02 Relief Valve Telltale Tubing Leak N/A
List of Air Contaminant Compounds - 14 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3 Butadiene 18.93 POUNDS 0.0   Not specifically authorized.
1-Butene 2.96 POUNDS 0.0   Not specifically authorized.
Acetylene 3.03 POUNDS 0.0   Not specifically authorized.
Benzene 11.19 POUNDS 0.0   Not specifically authorized.
Butane, N- 12.06 POUNDS 0.0   Not specifically authorized.
C6 (not including benzene) 2.46 POUNDS 0.0   Not specifically authorized.
Cis-2-butene 1.98 POUNDS 0.0   Not specifically authorized.
Ethylene 215.99 POUNDS 0.0   Not specifically authorized.
Isobutane 1.6 POUNDS 0.0   Not specifically authorized.
Isobutene 2.75 POUNDS 0.0   Not specifically authorized.
Pentenes 10.22 POUNDS 0.0   Not specifically authorized.
Propane 9.09 POUNDS 0.0   Not specifically authorized.
Propylene (Propene) 39.01 POUNDS 0.0   Not specifically authorized.
Toluene 1.13 POUNDS 0.0   Not specifically authorized.
5 - Emission Point Common Name: Emission Point Number:
Multi-Point Ground Flare FLAREXX2
List of Air Contaminant Compounds - 17 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 58.58 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
1-Butene 6.48 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Acetylene 13.67 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Benzene 26.81 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Butane, N- 6.77 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
C5s 20.57 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
C6+ 85.01 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Carbon Monoxide 24599.95 POUNDS 3742.46 LBS/HR Portions may be authorized under Permit# 102982.
Cis-2-butene 4.87 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Ethylene (gaseous) 1616.5 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Isobutane 0.03 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Isobutene 0.45 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Nitrogen Oxides 13321.12 POUNDS 2309.32 LBS/HR Portions may be authorized under Permit# 102982.
Propane 6.17 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Propylene (Propene) 57.95 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
Sulfur dioxide 1203.31 POUNDS 233.32 LBS/HR Portions may be authorized under Permit# 102982.
Trans-2-butene 3.47 POUNDS 3991.46 LBS/HR Portions may be authorized under Permit# 102982.
6 - Emission Point Common Name: Emission Point Number:
Primary Flare FLARE1
List of Air Contaminant Compounds - 16 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 736.08 POUNDS 709.48 LBS/HR 234.95 lbs of the total 736.08 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Acetylene 3.61 POUNDS 709.48 LBS/HR 1.33 lbs of the total 3.61 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Benzene 9.35 POUNDS 709.48 LBS/HR 4.44 lbs of the total 9.35 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Butane, N- 1163.91 POUNDS 709.48 LBS/HR 362.90 lbs of the total 1163.91 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C5s 14.85 POUNDS 709.48 LBS/HR 6.68 lbs of the total 14.85 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C6 (not including benzene) 2.06 POUNDS 709.48 LBS/HR 0.98 lbs of the total 2.06 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C7s 2.52 POUNDS 709.48 LBS/HR 1.20 lbs of the total 2.52 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Carbon Monoxide 5624.33 POUNDS 6627.58 LBS/HR 1650.05 lbs of the total 5624.33 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Cis-2-butene 45.16 POUNDS 709.48 LBS/HR 13.68 lbs of the total 45.16 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Ethylene 886.13 POUNDS 709.48 LBS/HR 348.00 lbs of the total 886.13 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutane 87.66 POUNDS 709.48 LBS/HR 31.43 lbs of the total 87.66 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutene 219.4 POUNDS 709.48 LBS/HR 53.20 lbs of the total 219.40 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Nitrogen Oxides 966.61 POUNDS 1630.75 LBS/HR 498.80 lbs of the total 966.61 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propane 383.32 POUNDS 709.48 LBS/HR 228.67 lbs of the total 383.32 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propylene (Propene) 2379.89 POUNDS 709.48 LBS/HR 1034.65 lbs of the total 2379.89 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Trans-2-butene 80.06 POUNDS 709.48 LBS/HR 19.63 lbs of the total 80.06 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
7 - Emission Point Common Name: Emission Point Number:
Secondary Flare FLARE2
List of Air Contaminant Compounds - 16 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 4469.64 POUNDS 709.48 LBS/HR 1058.88 lbs of the total 4469.64 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Acetylene 33.68 POUNDS 709.48 LBS/HR 10.98 lbs of the total 33.68 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Benzene 1616.46 POUNDS 709.48 LBS/HR 520.35 lbs of the total 1616.46 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Butane, N- 9737.12 POUNDS 709.48 LBS/HR 2117.78 lbs of the total 9737.12 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C5s 893.5 POUNDS 709.48 LBS/HR 291.09 lbs of the total 893.50 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C6 (not including benzene) 355.62 POUNDS 709.48 LBS/HR 114.48 lbs of the total 355.62 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
C7s 436.44 POUNDS 709.48 LBS/HR 140.49 lbs of the total 436.44 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Carbon Monoxide 46319.1 POUNDS 6627.58 LBS/HR 7399.11 lbs of the total 46319.10 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Cis-2-butene 317.21 POUNDS 709.48 LBS/HR 73.60 lbs of the total 317.21 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Ethylene 10924.81 POUNDS 709.48 LBS/HR 3887.94 lbs of the total 10924.81 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutane 599.7 POUNDS 709.48 LBS/HR 131.85 lbs of the total 599.70 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Isobutene 2098.63 POUNDS 709.48 LBS/HR 433.82 lbs of the total 2098.63 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Nitrogen Oxides 8125.04 POUNDS 1630.75 LBS/HR 2785.08 lbs of the total 8125.04 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propane 1664.71 POUNDS 709.48 LBS/HR 516.47 lbs of the total 1664.71 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Propylene (Propene) 17024.22 POUNDS 709.48 LBS/HR 4750.77 lbs of the total 17024.22 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Trans-2-butene 714.61 POUNDS 709.48 LBS/HR 152.32 lbs of the total 714.61 lbs are authorized under Permit #3452/PSD-TX-302M2/PAL6.
Cause of Emission Event or Excess Opacity Event, or Reason for Scheduled Activity:
Loss of utilities including, but not limited to, third-party nitrogen supply, third-party natural gas supply, and steam due to severe inclement weather causing the shutdown, idling, and/or transitioning to alternative operating conditions of multiple process units and safe utilization of the flare system.
Actions Taken, or Being Taken, to Minimize Emissions And/or Correct the Situation:
Operational adjustments were made and affected units were shut down, idled, or transitioned to other alternative operating conditions as safely as possible to minimize emissions. Ambient air quality monitoring performed by ExxonMobil indicates no adverse impact to the site and the surrounding community.
Basis Used to Determine Quantities and Any Additional Information Necessary to Evaluate the Event:
Portions of the unit emissions are authorized by Permit# 3452/PSD-TX-302M2/PAL6 and Permit# 102982. Emissions are based on process and engineering knowledge, analyzer data, flow meters, historical data, and/or AP-42 emission factors. Total emissions in the “Est. Quantity” column is the sum of authorized and unauthorized emissions. This event has ended.
Initial Notification Date/Time: 02/16/2021 12:14 AM Method: STEERS
Notification Jurisdictions: REGION 12 - HOUSTON
Publication Status: VERIFIED BY A CUSTOMER
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